Thank you for taking the time to help me with this. To answer your questions:
If I open a command window on the new DC I can ping, IP address, computer name and fqdn of the old DC.
Yes, first I joined the domain as a member server (via the properties of 'Computer' on the new DC, then changing from Workgroup to the domain).
Yes, when I ran DCPROMO, I specified only the IP address of the old DC as the DNS. Once promoted, I added the new DC IP address as the secondary DNS source.
Please explain where I need to go to view the DNS zones (and on what server). If I open the DNS Mnagement Console on the old DC I only see the original DC (Primus). Screen shot attached.
If I open the Network browser on a Vista PC on the network, whilst I can see the new DC (Zeus) it doesn't present Sysvol, Netlogin (just a folder that a shared). I can see the Sysvol. Netlogin on the old DC (Primus). See screen shot.
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