It seems that you have some problem related to the root path. After putting the correct root path your problem will be solved. Try the following code :
Code:
<ajax:ScriptManager ID="scriptManager" runat="server" ScriptPath="/" >
<Services>
<ajax:ServiceReference Path="~/Services/ProductService.asmx"/>
</Services>
<Scripts>
<ajax:ScriptReference Path="~/Catalog/Scripts/ProductControl.js"/>
</Scripts>
</ajax:ScriptManager>
After putting this code your, they will they are resolving to the http://localhost/mysite/products/ser...ctservice.asmx
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