Hey I did it many a times, its quite simple. Even recently I dragged the quick launch toolbar from the bottom of one monitor and then dropped it to the bottom of another monitor with the help of those two monitors connected on an ATI dual head card and with latest and most recent drivers installed. Initially I got the title bar but then when I moved it closer to the monitor edge, I got the toolbar as required that extends the entire width of the second monitor. Later on after the placement, I rebooted the system number of times in order to make sure that the positioning was successful.
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